Heterogeneous oxidation of cyclohexanone catalyzed by TS-1: Combined experimental and DFT studies
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چکیده
منابع مشابه
DFT studies on the heterogeneous oxidation of SO2 by oxygen functional groups on graphene.
The heterogeneous oxidation of SO2 has been the subject of intense scrutiny in atmospheric chemistry because of the adverse effects of sulfate particles. Although it has been found that the soot particles with a graphene-like structure play an important role in the oxidation of SO2, little is known about the atomic-level mechanism involved. Here, we studied the oxidation of SO2 on oxygen-functi...
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postnatal studies of bats (pipistrellus kuhlii and miniopterus schreibersii) & histomorphology and histochemistry studies of organs and diseases of (neurergus microspilotus and n. kaiseri)
1. to determine whether difference in birth body mass influenced growth performance in pipistrellus kuhlii we studied a total of 12 captive-born neonates. bats were assigned to two body mass groups: light birth body mass (lbw: 0.89 ± 0.05, n=8) and heavy birth body mass (hbw: 1.35 ± 0.08, n=4). heavier body mass at birth was associated with rapid postnatal growth (body mass and forearm length) ...
Selective Oxidation of Cyclohexane to Cyclohexanone
Cyclohexane oxidation is an important commercial reaction for the preparation of cyclohexanol and cyclohexanone, which are intermediates in the production of adipic acid and caprolactam respectively. These intermediates are important in the manufacture of nylon-6 and nylon-6,6 polymers (Yuan et al 2006 and Shylesh et al 2007). In addition, cyclohexanol and cyclohexanone are also used as solvent...
متن کاملDFT characterization of key intermediates in thiols oxidation catalyzed by amavadin.
Amavadin is an unusual octa-coordinated V(IV) complex isolated from Amanita muscaria mushrooms. The outer-sphere catalytic properties of such a complex toward several oxidation reactions are well known. Nevertheless, a remarkable example exists, in which the V(V) (d(0)) oxidized form of amavadin is able to electro-catalyze the oxidation of some thiols to the corresponding disulfides through an ...
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ژورنال
عنوان ژورنال: Chinese Journal of Catalysis
سال: 2015
ISSN: 1872-2067
DOI: 10.1016/s1872-2067(15)60859-2